Friday, May 8, 2015

Calculate Molarity(M) when 5g of NaOH is added in 200mL M/4 NaOH solution. Given Density of solution is 1.08 g/cm^3

The 200 mL solution of NaOH with a molarity of M/4 has a
density of 1.08 g/cm^3. The molarity of the solution is required after 5 g of NaOH is
added to it.


To determine the resultant molarity we do not
need the density of the solution. We need the molar mass of NaOH. Sodium hydroxide has a
molar mass of 40 g/mole. 5 g of NaOH is equivalent to 5/40 = 1/8
mole.


The original solution contained 1/4 mole of NaOH per
liter. 200 mL had 1/20 moles. On adding 1/8 mole, the total number of moles of NaOH in
the 200 mL of liquid is 1/20 + 1/8 = 7/40.


This gives a
molarity of (7/40)*1000/200 = 7/8


The resultant molarity of
the solution on adding 5 g of NaOH is 7/8 M.

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